Showing posts with label polymer material selection. Show all posts
Showing posts with label polymer material selection. Show all posts

Wednesday, 7 January 2026

5 Common Mistakes to Avoid When Selecting Polymers for Electric & Electronics Applications

Hello and welcome to a new post. In today’s post, we discuss five common mistakes to avoid when selecting polymers for electric and electronics applications such as connector housings.

Proper polymer material selection is the most effective antidote for battling plastic part failure and my aim is to help the plastics community to increase their confidence in material selection, especially with high performance polymers and recycling plastics. 

Avoid these 5 common mistakes when selecting polymers for electric and electronics applications

1️⃣ Ignoring Electrical Properties

-Failing to check dielectric strength, insulation resistance, and tracking resistance (CTI) can lead to electrical failures or safety hazards.

2️⃣ Overlooking Flame Retardancy Requirements

-Not verifying compliance with standards like UL 94 V-0 can result in non-compliant products and increased fire risk.

3️⃣ Neglecting Chemical and Environmental Resistance

-Forgetting to assess resistance to chemicals, moisture, and environmental stress can cause premature degradation, corrosion, or loss of performance.

4️⃣ Disregarding Dimensional Stability and Creep

-Choosing materials that warp, shrink, or deform under heat or load may compromise connector fit, function, and reliability over time.

5️⃣Underestimating Processability and Manufacturability

-Selecting polymers that are difficult to mold, have poor flow, or are incompatible with existing tooling can lead to defects, higher scrap rates, and increased production costs.

Figure 1: 5 common mistakes to avoid when selecting plastics for electrical applications.

Literature: 

[1] https://www.findoutaboutplastics.com/2025/04/nature-is-built-on-5-polymers-modern.html

Tuesday, 18 November 2025

Evaluating High-Temperature Performance: DMA Comparison of PARA-GF50 vs. PPA(4T)-GF50

Hello and welcome to a new blog post in which we evaluate the high-temperature performance of PARA (PA-MXD6) vs PPA.

When selecting materials for demanding, high-temperature applications, understanding their mechanical performance under heat is critical. Dynamic Mechanical Analysis (DMA) is a powerful tool for assessing how polymers retain their stiffness as temperatures rise. In this post, we compare the high-temperature behavior of two advanced engineering plastics: PA-MXD6-GF50 (50 wt% glass fiber reinforced Polyarylamide) and PPA(4T)-GF50 (50 wt% glass fiber reinforced Polyphthalamide). Both material fall into the category of semi-aromatic polyamides which reflect a resistance towards higher temperatures. In this post we check if this is the case for the both materials. 

DMA Results: Shear Modulus vs. Temperature

Figure 1 presents the dynamic shear modulus (E') of both materials as a function of temperature. The glass transition temperature (Tg) is a key indicator of when a polymer’s mechanical properties begin to decline:

  • PA-MXD6-GF50 (PARA): E' drops sharply at around 85°C, marking its Tg.
  • PPA(4T)-GF50: E' remains stable until approximately 125°C, indicating a higher Tg.

Beyond the glass transition, the differences become even more pronounced. Between 150°C and 200°C, PARA exhibits a slight plateau in modulus before dropping to zero at 250°C. In contrast, PPA(4T)-GF50 maintains a high modulus, retaining around 5 GPa even at 250°C. This demonstrates PPA’s superior ability to withstand elevated temperatures without significant loss of stiffness.

Figure 1: Comparison Dynamic Shear Moldulus E' of PARA-GF50 and PPA(4T).

Thermal Endurance: UL 746B RTI (Strength) Comparison

To further validate these findings, we examined the Relative Thermal Index (RTI, strength at 1.5 mm thickness) according to UL 746B:

  • PA-MXD6-GF50: RTI (strength) = 105°C
  • PPA(4T)-GF50: RTI (strength) = 130°C

The higher RTI value for PPA(4T)-GF50 confirms its suitability for applications requiring long-term mechanical integrity at elevated temperatures.

Ways to increase the thermal performance of PARA / MXD6

Increasing the thermal resistance of PARA/MXD6 can be done by blending PARA with PPE  (Polyphenylenether) and make a MXD6/PPE alloy which not only exhibits high temperature resistance, high strength, but also good and wear resistance.

Conclusion: Material Selection for High-Temperature Applications

DMA provides valuable insight into how materials behave under dynamic loading across a temperature range. For applications operating above 120°C, PPA(4T)-GF50 clearly outperforms PA-MXD6-GF50, maintaining higher modulus and demonstrating better thermal endurance. Alongside DMA, considering the RTI value is essential for making informed material choices in high-temperature environments.

In summary:

  • PPA(4T)-GF50 offers superior high-temperature performance and stability.
  • PA-MXD6-GF50 is suitable for applications up to its Tg and shows property loss at higher temperatures above 200°C.

Selecting the optimal material ensures reliability and safety in demanding thermal conditions. 

Nevertheless, PARA is outperforming PA and PPA in terms of stiffness, combined with excellent surface aesthetics and lowest water uptake allowing for high dimensional stable parts. 

More on PA-MXD6 / PARA here: 

Design Properties for Engineers: The ABCs of Polyarylamide (PARA; MXD6)

Polyarylamide vs Polyamide (PARA vs PA): What are the Major Differences Between PARA and PA (Polymer Material Selection Tip)?

Design Properties for Engineers: The ABCs of Polyarylamide (PARA; MXD6)

PA6.6 vs. PARA - Reducing the Wall Thickness of Injection Moulded Parts (Geometry Optimization Example)

Design Data for PolyArylAmide (PARA; PA MXD6) Selection: Mechanical Properties as Function of Temperature and Humidity

Mastering Injection Molding Tools for High Performance PolyArylAmide (PARA; PA MXD6): 6 Key Steps to Success

Design Properties for Engineers: Superior Gas Barrier Properties of PolyArylAmide (PARA; MXD6)

Check out my Micro Training below too:


And my dedicated Polyarylamide Hub here.

Thanks for reading & #findoutaboutplastics

Greetings,

Herwig Juster

Literature:

[1] https://www.syensqo.com/en/brands/ixef-para

[2] https://plasticsfinder.envalior.com/en/datasheet/ForTii%C2%AE+Ace+MX53/O4A8W

[3] https://www.nexeoplastics.com/types/plastics-database-datasheet?id=2131&product=Ixef%C2%AE&grade=1022

[4] https://www.orinkoplastic.com/PA-6I-6T-And-MXD6-pl60644367.html

[5] https://www.polyarylamide.com/


Wednesday, 3 September 2025

Turning Product Requirements into Plastic & Plastic Part Specifications: The Key to Successful Material Selection!

Hello and welcome to a new blog post where we discuss an important material selection topic. 

When developing a plastic part, clear and meaningful specifications are essential—they help control variations in function, appearance, and cost. By translating product requirements into detailed plastic specifications, you set the foundation for selecting the optimal material and ensuring consistent quality. Also, the specifications will help for sourcing plastic parts with the correct material. 

What should a robust plastic specification and plastic part specification include? 

✔️ Material brand, grade, and generic name (e.g., Ryton® R-4-200BL, PPS)

✔️ Surface finish

✔️ Desired parting line location

✔️ Flash limitations

✔️ Permissible gating and weld line areas

✔️ Void intolerance zones

✔️ Allowable warpage

✔️ Tolerances

✔️ Color

✔️ Decorating needs

✔️ Performance criteria

Example of turning a product requirement into a plastic specification:

If your product requirement is “the part must withstand high temperatures, needs to have low tolerance, and have a glossy black finish,” this translates into a plastic specification such as:

  • Material: Ryton® R-4-200BL (PPS) for heat resistance
  • Color: Black, high-gloss surface finish
  • Tolerance: ±0.05 mm
  • No voids allowed in load-bearing areas
  • Gating away from visible surfaces

Figure 1 demonstrates how plastic specifications act as a bridge between product requirements, material selection, and support for sourcing. First we turn product requirements into proper plastic specifications, which we can use for polymer selection. After identifying the plastic grade we can add it with commercial name to our specification list and use it for sourcing or to find alternativ materials, as well as sourcing the plastic parts themselfs. 

Figure 1: Plastic specifications as bridge between product requirements, material selection, and support for sourcing. 

Conclusions

Having proper specifications not only streamlines the material selection phase, but also greatly supports sourcing—especially when you need to identify or qualify alternative materials. Clear specifications ensure you can compare options confidently and maintain quality, even when supply chains change.

Getting these details right means your part will meet all functional, aesthetic, and economic goals. Start with clear specs—finish with a successful product!

Thanks for reading & #findoutaboutplastics

Greetings,

Herwig Juster

Literature:

[1] Herwig Juster - Polymer Material Selection, 2023

Sunday, 22 June 2025

Polymers and the Lindy Effect (Rule of Thumb Plastic Selection and Part Design)

Hello and welcome to a new Rule of Thumb post with focus on the Lindy Effect.

What is the Lindy Effect?

The Lindy Effect, when applied to polymers, suggests that the longer a polymer material or its application has been in use, the longer it is likely to continue to be used in the future. This effect highlights the idea that longevity in the face of time and competition implies robustness and adaptability, making older technologies or materials potentially more durable and relevant than newer, less tested alternatives. 

Examples - Polymers and the Lindy Effect

1. Established Polymer Applications: Consider the long-standing use of polyethylene (PE) in packaging or polyvinyl chloride (PVC) in construction as flame retardant flooring material as well as window frame polymer. The Lindy Effect would imply that these established uses are likely to continue for many years to come, as they have already demonstrated their longevity and reliability (Figure 1). 

Figure 1: Polymers and the Lindy Effect - Examples PVC and PE.

2. Mature Polymer Materials: Similarly, materials like natural rubber or certain types of thermosetting plastics, which have been used for a considerable time, are likely to remain relevant due to their proven track record. 

In essence, the Lindy Effect in the context of polymers suggests that the longer a polymer or its application has been around, the more likely it is to persist into the future. This is because its longevity indicates a degree of robustness and adaptability that makes it a reliable choice in the face of new innovations and changing needs. This brings me to one of my top 10 rules for plastic part design and selection (Rule Nr. 10): Past performance can be guarantee of future results. It can pay of to revisit past application designs to understand what worked in the past (materials selection and design).

Check out more Rules of Thumb in the "Start Here" section.

Thanks for reading & #findoutaboutplastics

Greetings, 
Herwig Juster

[1]  Nassim Nicholas Taleb (2012). Antifragile: Things That Gain from Disorder


Friday, 13 June 2025

High Performance Thermoplastic Selection - Polyether (PPE, PAEK, PEEK, PEKK) [Part 2C]

Hello and welcome to the Part 2C of our High Performance Thermoplastics selection blog series. Today we discuss Polyphenylene Ether (PPE) and PPE blends, their chemistry and production processes, their main properties, processing methods, and applications.

Overview - 6 major high performance thermoplastics families (“the magnificent six”) 

In this blog post series we discuss six major high performance thermoplastics families (“the magnificent six”) which are outlined in the following enumeration

1. Introduction to High Performance Polymers

2. Short profile of the "magnificent six" families:

-Part 2A: Polysulfides (Polyphenylene sulfide - PPS), Polysulfones (PSU, PESU, PPSU), and Polyarylates (PAR)

-Part 2B: Imide-Based Polymers (PEI, PAI, PESI, TPI, PI) and Polybenzimidazoles (PBI, PBI+PEEK, PBI+PEKK)

-Part 2C: Polyether (PPE, PAEK, PEEK, PEKK)

-Part 2D: Liquid Crystal Polymers (LCP) and High-performance Polyesters (Polycyclohexylene terephthalate - PCT)

-Part 2E: Semi- and Fully Aromatic Polyamides (PARA, PPA, Aramid)

-Part 2F: Polyhalogenolefins (PTFE, PCTFE, FEP, PVDF, ECTFE)

Polyphenylene Ether (PPE) and its Blends with Polystyrene (PS) and Polyamide (PA)

Polyphenylene ether (PPE), also known as polyphenylene oxide (PPO), is a high-performance thermoplastic polymer renowned for its excellent thermal, mechanical, and electrical properties. While pure PPE exhibits some processing challenges due to its high melt viscosity, blending it with polystyrene (PS) significantly improves its processability while retaining many of its desirable characteristics. These PPE/PS blends have become commercially significant engineering thermoplastics.   

Jack Welch's team at General Electric faced a challenge with Polyphenylene Oxide (PPO): its extremely high glass transition temperature (208°C) made it difficult to process without degrading the material (the methyl groups of PPE are expected to undergo autoxidation). An important key to future success was the research team around Dan Fox, Allan S. Hay, and E. M. Boldebuck, who found out the miscibility of PPO with PS first. To overcome this, they decided to blend PPO with polystyrene (PS). This clever solution allowed them to maintain many of PPO's desirable properties, lower the glass transition temperature,  while also making the material easier to process at lower temperatures and more cost-effective.

Chemistry and Production Process

1. Chemistry of Polyphenylene Ether (PPE)

The base polymer, PPE, is typically synthesized through an oxidative coupling polymerization of substituted phenols, most commonly 2,6-dimethylphenol (also known as 2,6-xylenol). This reaction is catalyzed by a copper-amine complex in the presence of oxygen. The general chemical structure of PPE can be represented as (Figure 1):

Figure 1: Chemical structure of the polymer Polyphenylene Ether (PPE) [1].

The ether linkages (-O-) in the polymer backbone, along with the aromatic rings and the methyl substituents, contribute to PPE's stiffness, thermal stability, and chemical resistance.

2. Production of PPE/PS Blends

The production of PPE/PS blends primarily involves melt blending the two polymers. This process is typically carried out in extruders or other intensive mixing equipment. The key steps include:
  • Raw Material Preparation: PPE and PS resins are typically received in pellet form. They may be dried to remove any moisture before blending.
  • Melt Blending: The PPE and PS pellets are fed into an extruder, where they are heated and mechanically mixed. The screw design and processing conditions (temperature, screw speed) are crucial for achieving a homogeneous blend. Compatibilizers, such as styrene-butadiene-styrene (SBS) or styrene-ethylene/butylene-styrene (SEBS) block copolymers, are often added to improve the compatibility between the relatively non-polar PS and the more polar PPE. These compatibilizers help to reduce interfacial tension and prevent phase separation, leading to enhanced mechanical properties.
  • Pelletizing: The molten blend exiting the extruder is then cooled and cut into pellets, which are the final product form for subsequent processing by manufacturers.
The ratio of PPE to PS in the blend can be varied to tailor the properties of the final material to specific application requirements. Higher PPE content generally leads to better thermal and mechanical performance, while higher PS content improves processability and reduces cost (Figure 2).   

Figure 2: Changing the glass transition temperature of PPE by changing the ratio of PPE and PS [1].


Main Properties of PPE/PS Blends

PPE/PS blends exhibit a combination of properties derived from both constituent polymers, often enhanced by the presence of compatibilizers. 

Key properties include:
  • Excellent Thermal Stability: PPE inherently possesses high glass transition temperatures (Tg ) and heat deflection temperatures (HDT). Blending with PS can reduce these values compared to pure PPE, however the blends still offer good high-temperature performance compared to many other engineering thermoplastics.   
  • Figure 3 shows the DMA of PPE+PS blend in comparison to High Impact Polystyrene (HIPS) and Polycarbonate (PC). PS has a glass transition temperature of about 100°C and up to this temperature PPE+PS can match PC in thermal performance (PC drops sharply at Tg of 147°C). There is no sharp drop in modulus observed with PPE+PS. 

Figure 3: Dynamic Mechanical Analysis (DMA) of PPE+PS vs HIPS vs PC. 

  • Good Mechanical Strength and Stiffness: PPE contributes to the blend's rigidity and strength. The impact strength can be tailored depending on the blend ratio and the use of impact modifiers.  
  • Excellent Electrical Insulation Properties: PPE is an excellent electrical insulator with a low dielectric constant and high dielectric strength, which are largely retained in the blends.   
  • Good Chemical Resistance: PPE offers good resistance to many chemicals, including acids, bases, and detergents. The chemical resistance of the blend is generally good but can be influenced by the PS content, which is more susceptible to certain solvents.   
  • High Stability towards Hydrolysis: hydrolysis resistance of PPE is superior when compared to other engineering plastics such as PBT and PA.
  • Improved Processability: The addition of PS significantly lowers the melt viscosity of PPE, making the blends easier to process using conventional methods like injection molding and extrusion.   
  • Dimensional Stability: PPE contributes to low water absorption and excellent dimensional stability, which is important for applications requiring tight tolerances.   
  • Flame Retardancy: PPE is inherently flame retardant. Blends often exhibit good flame retardant properties, especially when combined with flame retardant additives.   
Apart from blending PPE with PS; blends out of PPE with PA are possible too. PPE/PA blends have the following advantages: 
  • Combines Key Strengths: Blends the excellent dimensional stability, low water absorption, and heat resistance of PPE with the superior chemical resistance and flow of PA.
  • Enhanced Performance: The resulting material is exceptionally chemically resistant and boasts the stiffness, impact resistance, and heat performance needed for demanding applications like on-line painting.
  • Significant Weight Savings: Unfilled PPE/PA blends can offer part-weight reductions of up to 25% compared to glass or mineral-filled resins, thanks to their low density.
Outperforming properties of PPE/PS blends:  
  • Low specific gravity: 1.1 g/cm3. Most engineering polymers such as PC, PBT, and POM have a specific density of 1.2 g/cm3 and more. 
  • High self-extinguishing property: PPE has a high oxygen index (27-29) and it is easy to add flame resistancy. 
  • Excellent dielectric properties: PPE has a dielectric constant of 2.8 and a dielectric tangent of 6x1E-3. The dielectric breakdown strength (110 MV/m @ 0.5 mm thickness) is the highest among engineering plastics. 
  • High dimensional accuracy: PPE has one of the lowest coefficient of linear thermal expansion among engineering polymers (5.8 x 10E-5 1/°C).
Processing Methods

PPE/PS blends can be processed using various thermoplastic processing techniques, including:
  • Injection Moulding: This is the most common method for producing complex shaped parts from PPE/PS blends, leveraging their improved flow properties compared to pure PPE.
  • Extrusion: These blends can be extruded into profiles, sheets, and films for various applications.  
  • Blow Moulding: Certain grades of PPE/PS blends can be blow molded to produce hollow parts.
  • Thermoforming: Sheets extruded from PPE/PS blends can be thermoformed into various shapes. 
Applications of PPE/PS Blends

The unique combination of properties makes PPE/PS blends suitable for a wide range of applications across various industries:
  • Construction and Plumbing: Applications include pump housings, impellers, and other components requiring good mechanical and chemical resistance.
  • Automotive Industry: Interior and exterior components such as instrument panels, door panels, wheel covers, and electrical connectors benefit from the blends' thermal stability, dimensional stability, and impact resistance.   
  • Electrical and Electronics: Housings for electrical connectors, circuit breakers, switchgear, and other electrical components utilize the excellent electrical insulation properties and flame retardancy of PPE/PS blends.   
  • Household Appliances: Components for washing machines, dishwashers, microwave ovens, and other appliances benefit from the blends' heat resistance, chemical resistance, and good mechanical properties.
  • Business Equipment: Housings and internal components for computers, printers, and other office equipment utilize the blends' dimensional stability, electrical properties, and aesthetic appeal.   
  • Healthcare: Certain grades of PPE/PS blends can be used in medical devices and equipment due to their sterilizability and chemical resistance.   
Trade Names

Several companies market PPE/PS blends under various trade names. Some well-known examples include:
  • Noryl™: Formerly a trademark of GE Plastics, now owned by SABIC Innovative Plastics. This is one of the most widely recognized families of PPE-based resins, including various PPE/PS blends and other modifications.
  • XYRON™ from Japanese chemical company Asahi Kasei.
  • Various manufacturers such as Global Acetal (Lemalloy PPE) produce generic PPE/PS blends with specific property profiles.   
Economic Aspects

The market for PPE/PS blends is significant within the broader engineering thermoplastics market. The demand is driven by the increasing need for high-performance materials in automotive, electronics, plumbing and appliance industries.   
  • Cost Factors: The cost of PPE/PS blends is influenced by the price of the base polymers (PPE and PS), the concentration of PPE in the blend, the type and amount of compatibilizers and additives used, and the manufacturing process. Generally, higher PPE content leads to higher costs.
  • Market Trends: The trend towards lightweighting in the automotive industry and miniaturization in electronics continues to drive the demand for materials like PPE/PS blends that offer a balance of performance and processability. Growing environmental concerns are also pushing for more sustainable material solutions, which may influence the development of new PPE-based blends with recycled content or improved recyclability.
  • Regional Variations: The demand and market dynamics for PPE/PS blends can vary across different geographical regions based on industrial activity and specific application needs.
In conclusion, polyphenylene ether (PPE) and its blends with polystyrene and polyamide represent a versatile class of engineering thermoplastics offering a compelling combination of high-performance properties and improved processability. Their wide range of applications across various industries underscores their economic and technological significance in the world of polymer engineering. As a polymer engineering student, understanding the nuances of these materials will undoubtedly be valuable in your future endeavors.   

In the upcoming Part 2C we will continue to discuss the Polyether high performance polymers such as PAEK, PEEK, and PEKK.

Thanks for reading & #findoutaboutplastics

Greetings, 
Herwig Juster

Literature: 

[1] Allan S. Hay: Polymerization by Oxidative Coupling: Discovery and Commercialization of PPO and Noryl Resins

[2] https://www.sabic.com/en/products/specialties/noryl-resins

[3] https://www.gpac.co.jp/en/product/lemalloy/

[4] https://www.findoutaboutplastics.com/2016/09/jack-welch-and-his-uprise-in-ge.html

[5] https://www.findoutaboutplastics.com/2024/08/high-performance-thermoplastic.html


Monday, 5 May 2025

4 Tips for Effective Polymer Material Selection

Hello and welcome to a new post and today I present to you 4 tips for effective polymer material selection. In the realm of plastic product development and engineering, the selection of the appropriate polymer material stands as a pivotal decision, directly influencing the functionality, durability, cost-effectiveness, and overall success of the final product. 

Navigating the vast landscape of available plastics and their diverse properties can feel like traversing a complex terrain. To ensure optimal outcomes, a structured and thoughtful approach is paramount. This guide illuminates four essential tips that will empower engineers and designers to make informed and effective polymer material selections, laying the groundwork for robust and reliable applications.

Let us geht started!

1. Requirement Analysis

  • Map out the true part functions, load cases, and material requirements.
  • Consider industry standards for properties like flammability, thermal, and electrical characteristics.
  • Include qualitative properties such as haptic perception and optical qualities.
  • Address legal aspects, manufacturing processes (e.g., injection molding, extrusion), and expected costs.
  • Prioritize requirements and summarize them in a worksheet or product requirement document (PRD).

2. Questioning

  • Ask relevant questions related to the requirements, such as:
    • End-use conditions (indoor/outdoor).
    • Temperature requirements (minimum, maximum, continuous use).
    • Chemical exposure (splash resistance or full submersion).
    • Mechanical exposure (load cases, repeatable or static loads).
  • These questions help in understanding the requirements better.
  • A more detailed list can be found here (incl. download): Material Selection Requirements Checklist

3. Resin Neutral Approach

  • Challenge the use of established materials by exploring other material opportunities.
  • Question the reasons behind choosing specific resins and whether they truly meet the requirements.
  • Encourage re-evaluation of legacy materials and consider alternatives.

4. Decision Making Tools

  • Use tools like decision matrix analysis to rank pre-selected materials based on their properties and requirement fulfillment.
  • A detailed explanation can be found here
  • These tools provide documentation and help understand decisions made by others.

Conclusion

Mastering the art of polymer material selection is an ongoing process of learning and refinement. By diligently applying these four tips – thorough requirement analysis, insightful questioning, maintaining a resin-neutral perspective, and leveraging decision-making tools – you can significantly enhance the effectiveness of your material choices. Embracing this structured approach not only leads to better performing and more cost-efficient products but also fosters a deeper understanding of material science and engineering principles within your team. Ultimately, the thoughtful and informed selection of polymers is a cornerstone of innovation and a key driver in creating successful and sustainable solutions for a wide range of applications.

Ready to begin your journey to Polymer Mastery? Take the Polymer Material Selection scorecard today and discover your POMS score!

Polymer Material Selection scorecard

Also, you can get familiar with the 6 essential polymer material selection skills here

My post on 10+ key considerations for selecting the optimal polymer material can help to kickstart your material selection journey too. 

Thanks for reading and #findoutaboutplastics

Greetings

Literature: 

[1] https://www.polymermaterialselection.com/plastic-selection-tools

[2] https://www.findoutaboutplastics.com/2025/03/become-master-in-polymer-material.html

[3] https://public.tableau.com/app/profile/herwig.juster/vizzes


Wednesday, 23 April 2025

The Path to Polymer Selection Mastery: A Jedi's Journey

Hello and welcome to this new post, today in the theme of Star Wars, together with polymer material selection

FindOutAboutPlastics.com presents: The Path to Polymer Selection Mastery - A Jedi's Journey.

The path to becoming a master of polymer material selection is a challenging one, requiring dedication, perseverance, and a deep understanding of the Force, or in this case, the properties of plastics. Just as a Padawan must undergo rigorous training and face numerous trials to become a Jedi Knight, so too must an aspiring polymer engineer navigate a series of challenges to master the art of material selection.

This journey begins with a thorough understanding of the fundamental principles of polymer science, including the various types of polymers, their structures, and their unique properties. It is akin to a Padawan learning the basics of lightsaber combat and the Force. From there, the aspiring engineer must delve into the intricate details of polymer behavior, exploring how different polymers react under various conditions, such as heat, stress, and chemical exposure. This is similar to a Padawan mastering the subtle nuances of the Force, understanding its power and limitations.

The next step involves applying this knowledge to real-world applications, selecting the most suitable polymer for a specific purpose. This is where the true test of skill lies, as the engineer must weigh various factors, such as cost, performance, and environmental impact, to make the optimal choice. This is analogous to a Jedi Knight facing a dangerous mission, where they must use their knowledge and skills to overcome obstacles and achieve their goal.

Finally, the journey culminates in mastery, where the engineer can seamlessly integrate their knowledge of polymer science with their understanding of engineering principles to create innovative and sustainable solutions. This is akin to a Jedi Master, who has achieved enlightenment and can use the Force for the greater good.

In essence, becoming a master of polymer material selection is a continuous learning process, requiring a combination of theoretical knowledge, practical experience, and a deep understanding of the challenges and opportunities that lie ahead. It is a journey that demands dedication, perseverance, and a willingness to embrace the unknown, just as it does for a Padawan seeking to become a Jedi Master.

The path to polymer mastery may be arduous, but the rewards are great. Those who persevere will gain the ability to shape the future, creating products that are not only functional but also sustainable and beneficial to society. So, embrace the challenge, hone your skills, and embark on your journey to polymer mastery.

Ready to begin your journey to Polymer Mastery? Take the Polymer Material Selection scorecard today and discover your POMS score!

Polymer Material Selection scorecard

Also, you can get familiar with the 6 essential polymer material selection skills here

Thanks for reading and #findoutaboutplastics

Greetings

[3] https://public.tableau.com/app/profile/herwig.juster/vizzes


Tuesday, 1 April 2025

Nature is built on 5 Polymers. Modern life is built on over 200 different Polymers - How to select the right one?

Hello and welcome to a new post. Today I would like to start with a quote of mine: 

"Nature is built on 5 polymers. Modern life is built on over 200 different polymers. Therefore, optimal polymer selection is key for successful applications and to prevent plastic part failure in the long run." 

"Nature works with 5 polymers," is a statement from Mrs. Janine Benyus and reflects a key concept in her advocacy for biomimicry. It highlights the efficiency and elegance of natural systems compared to human industrial processes. Here's a breakdown of what she means:

Polymers in Nature:

Polymers are large molecules made up of repeating smaller units. They are the building blocks of many materials. Nature primarily uses a limited set of these polymers to create a vast array of structures and functions.

These "five polymers" generally refer to:

  • Cellulose: Found in plant cell walls, providing structural support. Cellulose was used in the past to create one of the first human made plastics: Celluloid. It is made by mixing nitrocellulose and camphor.
  • Chitin: Forms the exoskeletons of insects and crustaceans, as well as fungal cell walls.
  • Lignin: A complex polymer that provides rigidity to plant cell walls, particularly in wood.
  • Proteins: Versatile polymers that perform a wide range of functions, from structural support to enzymatic activity.
  • Nucleic acids (DNA and RNA): Carry genetic information.
5 Natural Polymers: Cellulose, Chitin, Lignin, Proteins and Nucleic Acids [1].

Biomimicry Application:

Benyus's statement encourages us to look to nature for inspiration in materials science.

By mimicking the way nature uses these polymers, we can create materials that are:

  • Stronger
  • More durable
  • More sustainable
  • Easier to recycle.

In essence, "Nature works with five polymers" is a powerful reminder of nature's ingenuity and a call to action for us to learn from its wisdom.

Modern life is built on over 200 different polymers - How to select the right one? 

An important step in the selection journey are the mastering of the what i refer to as the 6 Polymer Material Selection skills (6 POMS skills; Figure 1): 
P- Properties: Understanding key polymer properties
P - Part Design: Defining Application Requirements for Plastic Part Design
P - Polymer material values: Translating application requirements to qualitative and quantitative material values
P - Process: Polymer material selection process
P - Performance: Evaluation of material and part performance
P - Plastic supplier: Selection of material and supplier

Figure 1: Overview of the 6 Polymer Material Selection skills. 

Check out the detailed description of the 6 POMS here

In order for you to assess where you are currently ranking at the 6 POMS skills, I created a simple scorecard consisting out of 26 Yes / No questions and after completing the questionnaire, you receive an overall POMS score and detailed scores for each of the six critical elements of polymer material selection.

Also, you get a customised report with actionable steps to immediately start improving your POMS score and your impact in the field of polymer material selection.

A quick 5-step selection guide
Selecting the optimal thermoplastic material can be challenging and my aim is to provide you with a practical guide which leads you fast through the selection journey. 
Improper selection of plastics for the application is the leading cause for plastic part failure and since most parts fail along weld lines or knit lines, optimal mould design including filling and processing of the part are crucial too. 

Apart from the 200 polymers,  there are almost 100 generic “families” of plastics and additionally blending, alloying, and modifying with additives results in 1,000 sub-generic plastic types. Also, selecting the wrong polymer for your product may result in additional financial resources, since the selection process needs to be repeated (including making new tools) or even worse, product failure leads to claims and recalls. The following guide will help you to prevent the major mistakes and if you want to be sure, you can always reach out to a plastic expert to review your selection or help you to select the optimal grade.

What are the 5-steps (download here the guide): 

1. Define Application Requirements: In the first step we lay out all the application requirements and focus on Function, Loading Conditions, Environmental Factors, Regulatory Requirements, and Processing Considerations. A suitable acronym for this step is called FLERP:  F- Function; L- Loading conditions; E - Environmental Factors; R- Regulatory requirements; P- Processing requirements.

2. Identify Candidate Materials: Based on your application requirements, research potential engineering plastics that possess the necessary properties. Material selection charts and dashboards, supplier websites, and technical data sheets can be helpful resources. Consider factors like: Mechanical properties (short- and long-term; as a function of time and different temperature levels), thermal properties, chemical resistance, electrical properties, processing characteristics, and cost. 

3. Evaluate Material Performance: 
Carefully review technical data sheets from potential suppliers to understand the specific properties of different plastic grades within a material family. Most of the time only a single temperature is covered (room temperature). This is useful for comparing different material data sheets to each other, however for part design it has its limitations. Also, consider Multipoint Design Data which helps to think in time-dependency and temperature-dependency behaviors. Graphically such behaviors can be better accessed. Utilizing CAE software to simulate the filling of your part as well as the performance of your design using different material options.

4. Additional Considerations: Consider processing methods and cost. Evaluate environmental and regulatory factors.
Consider the material availability in order to ensure the chosen material is readily available from reliable suppliers. Additionally, evaluation of the environmental impact of the material, including its recyclability or biodegradability, if applicable can be done. Long-term performance check is needed to check the  material's resistance to degradation and expected lifespan in your application. 

5. Testing and validation. 
In the last step, prototyping is done. You can start by obtaining samples from material suppliers for simple analysis.
Next is to create prototypes using the previous identified candidate materials to test performance under real-world conditions. After concluding the final tests, final material selection can be done and a suitable supplier of the material chosen. 

6. Bonus Consult with Plastic Experts and Material Suppliers:
Discuss your application requirements with experienced polymer engineers and material suppliers. Seek recommendations based on their expertise and access to the latest materials.

My Polymer Selection Funnel Method

For a more detailed selection approach, as mentioned before,  I created the Polymer Selection Funnel methodology (POMS-Funnel).  Figure 2 presents the four different stages of the material selection funnel as well as the tools we can use to facilitate the selection. We can use this as a guideline throughout the selection journey.

Figure 2: Overview of the Polymer Selection Funnel method. 

Funnel stage 1: Material selection factors
In this first stage we map out the true part functions and material requirements. After this we translate the requirements into material selection factors.

Funnel stage 2: Decision on thermoplastic or thermoset
After translating the requirements into material selection factors, the first decision is made:
Which is the most suitable polymer chemistry to fulfill the listed requirements and selection factors? Thermoplastics or thermosets?

Funnel stage 3: Selection discussion with worksheet (qualitative matrix analysis)
The third funnel stage represents a core element in the whole material selection funnel. It is a detailed selection discussion with a worksheet. I call it the decision matrix analysis and it ranks all of the pre-selected polymers. The decision matrix analysis consists of five steps. The base calculation principle is a scoring of each of the pre-selected materials for each of the material selection factors. In the end we add up all weighted scores for each material. The material with the highest score is most suitable for selection and further investigation in the fourth stage.

Funnel stage 4: Testing, selection of material and vendor
In the last funnel stage, we would like to know in detail how the materials with the highest scores perform as a final part in a system of plastic parts or as a single plastic part alone. After all the tests are done and the material has passed all tests, commercial conditions with the material supplier can be finalized and first small serial production can start.

For better remembering all the Funnel stages, i created an acronym which plays directly on the word PLASTic, giving the methodology immediate domain recognition for polymer engineers:

P.L.A.S.T (Parameters, Logic Choice, Analytical Matrix, System Testing)

P — Parameter Definition (Stage 1)

L — Logic Choice: Thermoplast/Thermoset (Stage 2)

A — Analytical Matrix Analysis (Stage 3)

S — System & Vendor Testing (Stage 4)

I created a dedicated page for Polymer Material Selection which contains all you need for your material selection, from taking the scorecard test, online selection tools, and examples which have used the POMS funnel method. 

If you want to see the POMS funnel method in action, check out this example: Base plate of a filter coffee machine.

Sketchnote as a summary of the framework and post.


Conclusion

In material selection, there is no "one-size-fits-all" solution. The optimal material will depend on the unique needs of your specific application. A balance between performance, cost, and processing is often necessary. By following a five step guide or the POMS funnel method, leading to a thorough evaluation, you can make an informed decision and select the optimal engineering plastic for your project!

Literature: 
[1] https://www.amazon.de/-/en/Janine-M-Benyus/dp/1094025003
[3] https://www.polymermaterialselection.com/

Tuesday, 4 March 2025

Become a Master in Polymer Material Selection - Learn & Apply the “6 POMS” Skills

Hello and welcome to a new blog post. Over the course of my career as a polymer engineer, I have sought to delineate the requisite skills for effective polymer material selection. Through discussions with polymer engineers responsible for successful plastic product development over the past decade, it has become evident that proficiency in six distinct areas is consistently demonstrated. These individuals not only possess comprehensive knowledge but also apply it rigorously across multiple product development cycles. Through iterative refinement and detailed analysis, these six areas have been systematically mapped. Consequently, I have formalized these competencies into what I now refer to as the "6 POMS" skills (Figure 1).

The 6 Polymer Material Selection Skills

Figure 1: Overview of the 6 POMS skills helping to become a Master in polymer material selection [1].

Let us discuss each of the 6 P's:

P- Properties: Understanding key polymer properties 

To effectively select polymers for specific applications, a thorough understanding of their key properties is essential. This includes familiarity with polymer structure properties like morphology, molecular weight, and thermal transitions. Knowledge of mechanical properties such as tensile, flexural, and impact strength, stiffness, and elongation is crucial. Additionally, a grasp of thermal properties, including glass transition temperature (Tg), melting temperature (Tm), and heat resistance, is necessary. The ability to assess chemical resistance to acids, bases, solvents, and oxidation is also vital. Furthermore, awareness of both long-term and short-term properties and their relationship to application requirements is paramount. Finally, understanding multi-point property data and its relevance to application needs ensures optimal material selection.

P - Part Design: Defining Application Requirements for Plastic Part Design 

The success of a plastic part depends heavily on its ability to meet the specific demands of its intended application. To ensure this, a structured approach to defining requirements is essential. This involves using tools like requirement checklists and methodologies such as the FLERP approach (Function, Loading conditions, Environmental Factors, Regulatory requirements, and Processing requirements).

A crucial aspect of this process is the ability to write clear and concise product specifications. This requires a deep understanding of the part's true functions, load cases, and material requirements. Additionally, it is important to consider the data needed for plastic part design, including material properties, processing parameters, and environmental factors.

Finally, cost considerations should be integrated throughout the design process. This involves evaluating material and manufacturing costs to optimize the overall design and ensure economic viability. By following these steps, engineers can effectively define application requirements and design plastic parts that meet the needs of their intended use.

P - Polymer material values: Translating application requirements to qualitative and quantitative material values

Translating plastic application requirements into actionable material values is a critical step in the selection process. This involves understanding how qualitative and quantitative application needs correspond to specific material properties. A systematic approach, such as listing all application requirements and their translated material values in a dedicated system or sheet, significantly enhances the selection process by providing a clear and organized framework for evaluation.

P - Process: Polymer material selection process

The process of selecting polymer materials involves several key considerations. It's important to determine if a structured, step-by-step approach is currently in place. Utilizing online databases like CAMPUS or Omnexus for material identification is common practice. A fundamental understanding of how to interpret technical datasheets for plastics is also crucial. Furthermore, the selection process should involve a degree of critical thinking, including challenging the use of established materials and exploring alternative options. Questioning the rationale behind choosing specific resins and ensuring they align with actual requirements is vital. Finally, the use of decision-making tools can significantly facilitate the selection of appropriate plastics.

P - Performance: Evaluation of material and part performance

Evaluating plastic material and part performance requires a comprehensive approach. Utilizing CAE tools, like injection mould filling simulation and FEA, enables virtual testing and optimization of plastic parts. Familiarity with standard ISO tests, such as tensile tests, is essential for quantifying material properties. Physical prototyping plays a critical role in verifying material and part functionality. Ultimately, experience in testing both material and part performance is crucial to confirm the suitability of the chosen plastic for its intended application.

P - Plastic supplier: Selection of material and supplier

The selection of plastic materials and suppliers involves active engagement and collaboration. Regularly discussing application requirements with polymer application engineers is crucial for ensuring material suitability. Direct contact with material suppliers to obtain samples supports the selection process by allowing for physical testing and evaluation. Seeking recommendations from plastics experts and material suppliers on new material developments ensures access to the latest advancements and potential solutions.

How to train the 6 POMS skills and become a master in polymer material selection? 

Start by taking my new developed Polymer Material Selection test and discover your polymer material selection score. Assess where you are currently ranking at the different POMS skills and increase your ability to select plastics better. It is a simple test which consists of 26 Yes/No questions. After submitting, you will receive a report containing your overall POMS score, the detailed score and recommendations for improvements.

I invite you to take the test, get your POMS-score and review the suggested improvements.

Thanks for reading & #findoutaboutplastics!

Greetings, 

Herwig 

New to my Find Out About Plastics Blog - check out the start here section


Literature: 

[1] https://www.polymermaterialselection.com/poms-score

[2] https://www.amazon.de/-/en/Polymer-Material-Selection-practical-systematic/dp/B0BSWM6BPD