Sunday, 14 December 2025

Practical Bio ABS Selection Guide Including Example (Housing of CHIMEI Ballpoint Pen)

Hello and welcome to a new blog post on selecting bio-based ABS materials for consumer applications. In the first section, I provide you with an overview on what to consider when selecting a bio-based material in general, and in the second section I discuss the housing of a ballpoint pen made out of bio-based ABS from CHIMEI.  

Selection of bio-based ABS plastic

When selecting a bio-based ABS plastic, consider its performance properties like impact resistance and temperature stability, its processability, and its end-of-life options, such as biodegradability or recyclability. You should also evaluate factors like cost, regulatory compliance (e.g., food contact), and sustainability claims using a method like a life cycle assessment (LCA) to ensure it meets your specific needs and environmental goals. 

Performance and functionality

  • Mechanical Properties: Compare the bio-based plastic's tensile strength, impact toughness, and ductility to conventional ABS to ensure it can withstand the application's stress.
  • Thermal Properties: Evaluate its operating temperature range, heat deflection temperature, and coefficient of thermal expansion (CTE) to prevent warping and ensure it's suitable for the intended environment.
  • Chemical Resistance: Determine if the bio-based plastic is resistant to the chemicals it will be exposed to. Some are sensitive to certain solvents, acids, or alkalis. 

Processability

  • Processing Methods: Check if the material is compatible with existing processing equipment, such as injection molding or 3D printing, and has a controllable melt behavior to reduce issues like warpage.
  • Additives: Be aware that additives, like silica, can affect properties. For instance, silica can improve strength but may increase brittleness.
  • Melt and Glass Transition Temperatures: Understand the material's specific temperatures for extrusion or printing, which will be different from fossil-based ABS. 

Sustainability and end-of-life

  • Bio-based content: Not all "bio-based" plastics are 100% derived from renewable sources. The bio-based content is an important metric, and certifications may require a minimum percentage to be considered eco-friendly.
  • Biodegradability: Bio-based does not automatically mean biodegradable. Verify if the material is compostable or biodegradable and what the specific requirements are for degradation.
  • Recyclability: Confirm if the material can be recycled and what infrastructure exists for recycling it.
  • Life Cycle Assessment (LCA): Use LCA to quantitatively compare the environmental impact of different bio-based options against each other and against traditional plastics across their full life cycle. 
  • End-of-life options: Bio-based does not mean biodegradable. Clarify the appropriate end-of-life pathway, which may include industrial recycling or composting, and ensure the necessary infrastructure exists in your region.
  • Sustainable sourcing: Investigate the sourcing of the bio-based feedstock to avoid competition with food and water resources or negative impacts on land use and biodiversity.
  • Supplier transparency: Work with suppliers and distributors that provide clear, detailed documentation on the formulation, sourcing, and environmental standards (like ISO 14001, REACH, or RoHS). 

Business and market considerations

  • Cost: Bio-based ABS is often more expensive than traditional ABS, though costs are expected to decrease as technology advances and production scales. Weigh the potentially higher material cost against the long-term value, including sustainability goals and customer demand.
  • Supplier reliability: Ensure the supplier can provide a consistent and reliable supply of material. Factors like agricultural yields and refining efficiencies can affect the availability and price of bio-based feedstocks.
  • Regulatory compliance: Confirm that the material meets all relevant regulations and standards for your application, such as FDA compliance for food contact or specific certifications for the automotive or electronics industries.
  • Consumer perception: Consider how your customers will perceive the new material. Use certifications and clear communication to market the product's environmental benefits accurately and transparently.

Industry example - CHIMEI Ecologue™ Bio ABS Material for Ballpoint Pen Housing

Wen-long Hsu (่จฑๆ–‡้พ) founded CHIMEI Corporation, a Taiwanese company that became a leading producer of ABS (Acrylonitrile Butadiene Styrene) plastic, a versatile and durable material used in many products. Mr. Hsu was known for his business acumen and his commitment to social responsibility, which included prioritizing the welfare of his employees and funding the creation of the CHIMEI Museum. The history of CHIMEI ABS is therefore the story of a successful business built by Mr. Hsu Wen-long on a foundation of ethical business practices and a vision for social contribution. 

At K Fair 2025 I was introduced to Mr. Yu-Ching Yang, Director of Sales Division from CHIMEI and he gave me a special gift: a ballpoint pen made out of bio-based ABS (Figure 1). 

What makes it so special? 

Figure 1: Ballpoint pen housing made out of Ecologue™ Bio ABS.

It is made out of their Ecologue™ Bio ABS. Instead of fossil based feedstock, Ecologue™ Bio ABS uses bio-attributed feedstock, allowing for product carbon footprint (PCF) reduction of 122% compared to fossil based ABS (Figure 2). Such an impressive reduction is achieved by using biomass residues or wastes as the feedstock and enhancing circularity.

Figure 2: Emission comparison of fossil-based ABS vs. CHIMEI bio-based ABS.

Key Takeaways for Selecting Bio-Based ABS Plastics

Performance Must Match Application Needs:
When considering bio-based ABS, ensure its mechanical, thermal, and chemical properties are suitable for your specific application. Not all bio-based alternatives perform identically to conventional ABS, so thorough testing and comparison are essential.

Sustainability Claims Require Scrutiny:
“Bio-based” does not always mean biodegradable or fully renewable. Always verify the actual bio-based content, recyclability, and end-of-life options. Use tools like Life Cycle Assessment (LCA) to objectively evaluate environmental impact and ensure the chosen material aligns with your sustainability goals.

Business and Compliance Factors Matter:
Evaluate the cost, supplier reliability, and regulatory compliance of bio-based ABS. Transparent documentation and certifications are crucial for both market acceptance and meeting industry standards.
All over, keep a holistic approach—balancing performance, sustainability, and business needs—when selecting bio-based ABS plastics next time.

Thank you for reading & #findoutaboutplastics
Greetings, 
Herwig 

Literature: 
[1] https://www.chimeicorp.com/en-US?page=article&id=641137a3909e10048d14afca
[2] https://salesplastics.com/abs-plastic/#:~:text=ABS%20maintains%20stability%20across%20a,and%20thermal%20degradation%20during%20processing.


Friday, 12 December 2025

How to Mark Plastic Parts with Recycled Content: A Quick Guide to ISO 1043 & ISO 11469

Hello and welcome to a new blog post on plastic part marking. As the plastics industry moves toward a circular economy, clear and standardized part marking is more important than ever—especially when using recycled materials. ISO 1043 and ISO 11469 provide the global framework for material identification and marking, helping manufacturers, recyclers, and end-users quickly recognize what’s in a plastic part.

Here’s how to apply these standards when your part contains recycled material (Figure 1):

1. Basic Material Identification

  • Use angle brackets to indicate the polymer type.
    • Example: >ABS< for acrylonitrile-butadiene-styrene.

2. Declaring Recycled Content

  • If your part includes recycled material, you have several marking options:
    • No specific claim:
      >ABS<
      (Use this when you don’t want to declare recycled content.)
    • General claim of recycled content:
      >ABS(REC)<
      (Use this to indicate the presence of recyclate, without specifying the amount.)
    • Specific claim with minimum percentage:
      >ABS(RECx)<
      (Replace “x” with the minimum percentage by mass. For example, >ABS(REC30)< means at least 30% recycled content.)

3. Marking Polymer Blends and Alloys

  • For blends, list the main polymer first, followed by the secondary polymer:
    • Example: >PC+ABS< for a polycarbonate and ABS alloy.
  • To declare recycled content in a blend:
    • Example: >PC+ABS(REC30)< for a blend with at least 30% recycled content.

Figure 1: Applying ISO 1043 for plastic part marking when containing recycled materials.

Why does this matter?
Consistent and transparent marking supports efficient recycling, traceability, and compliance with sustainability goals. It also helps customers and recyclers make informed decisions—boosting the value of recycled plastics in the marketplace.

In summary:
When designing plastic parts with recycled content, follow ISO 1043 and ISO 11469 for clear, standardized marking. It’s a small step that makes a big difference for the circular plastics economy!

Check out my detailed guide on ISO 1043 plastic part marking codes here.

Thanks for reading & #findoutaboutplastics

Greetings,

Herwig Juster

Literature: 

[1] https://www.findoutaboutplastics.com/2020/12/plastic-part-marking-overview-codes-and.html

[2] https://cdn.standards.iteh.ai/samples/63434/f460de8a1261420a92f1195a8e329213/ISO-11469-2016.pdf


Tuesday, 18 November 2025

Evaluating High-Temperature Performance: DMA Comparison of PARA-GF50 vs. PPA(4T)-GF50

Hello and welcome to a new blog post in which we evaluate the high-temperature performance of PARA (PA-MXD6) vs PPA.

When selecting materials for demanding, high-temperature applications, understanding their mechanical performance under heat is critical. Dynamic Mechanical Analysis (DMA) is a powerful tool for assessing how polymers retain their stiffness as temperatures rise. In this post, we compare the high-temperature behavior of two advanced engineering plastics: PA-MXD6-GF50 (50 wt% glass fiber reinforced Polyarylamide) and PPA(4T)-GF50 (50 wt% glass fiber reinforced Polyphthalamide). Both material fall into the category of semi-aromatic polyamides which reflect a resistance towards higher temperatures. In this post we check if this is the case for the both materials. 

DMA Results: Shear Modulus vs. Temperature

Figure 1 presents the dynamic shear modulus (E') of both materials as a function of temperature. The glass transition temperature (Tg) is a key indicator of when a polymer’s mechanical properties begin to decline:

  • PA-MXD6-GF50 (PARA): E' drops sharply at around 85°C, marking its Tg.
  • PPA(4T)-GF50: E' remains stable until approximately 125°C, indicating a higher Tg.

Beyond the glass transition, the differences become even more pronounced. Between 150°C and 200°C, PARA exhibits a slight plateau in modulus before dropping to zero at 250°C. In contrast, PPA(4T)-GF50 maintains a high modulus, retaining around 5 GPa even at 250°C. This demonstrates PPA’s superior ability to withstand elevated temperatures without significant loss of stiffness.

Figure 1: Comparison Dynamic Shear Moldulus E' of PARA-GF50 and PPA(4T).

Thermal Endurance: UL 746B RTI (Strength) Comparison

To further validate these findings, we examined the Relative Thermal Index (RTI, strength at 1.5 mm thickness) according to UL 746B:

  • PA-MXD6-GF50: RTI (strength) = 105°C
  • PPA(4T)-GF50: RTI (strength) = 130°C

The higher RTI value for PPA(4T)-GF50 confirms its suitability for applications requiring long-term mechanical integrity at elevated temperatures.

Ways to increase the thermal performance of PARA / MXD6

Increasing the thermal resistance of PARA/MXD6 can be done by blending PARA with PPE  (Polyphenylenether) and make a MXD6/PPE alloy which not only exhibits high temperature resistance, high strength, but also good and wear resistance.

Conclusion: Material Selection for High-Temperature Applications

DMA provides valuable insight into how materials behave under dynamic loading across a temperature range. For applications operating above 120°C, PPA(4T)-GF50 clearly outperforms PA-MXD6-GF50, maintaining higher modulus and demonstrating better thermal endurance. Alongside DMA, considering the RTI value is essential for making informed material choices in high-temperature environments.

In summary:

  • PPA(4T)-GF50 offers superior high-temperature performance and stability.
  • PA-MXD6-GF50 is suitable for applications up to its Tg and shows property loss at higher temperatures above 200°C.

Selecting the optimal material ensures reliability and safety in demanding thermal conditions. 

Nevertheless, PARA is outperforming PA and PPA in terms of stiffness, combined with excellent surface aesthetics and lowest water uptake allowing for high dimensional stable parts. 

More on PA-MXD6 / PARA here: 

Design Properties for Engineers: The ABCs of Polyarylamide (PARA; MXD6)

Polyarylamide vs Polyamide (PARA vs PA): What are the Major Differences Between PARA and PA (Polymer Material Selection Tip)?

Design Properties for Engineers: The ABCs of Polyarylamide (PARA; MXD6)

PA6.6 vs. PARA - Reducing the Wall Thickness of Injection Moulded Parts (Geometry Optimization Example)

Design Data for PolyArylAmide (PARA; PA MXD6) Selection: Mechanical Properties as Function of Temperature and Humidity

Mastering Injection Molding Tools for High Performance PolyArylAmide (PARA; PA MXD6): 6 Key Steps to Success

Design Properties for Engineers: Superior Gas Barrier Properties of PolyArylAmide (PARA; MXD6)

Check out my Micro Training below too:


And my dedicated Polyarylamide Hub here.

Thanks for reading & #findoutaboutplastics

Greetings,

Herwig Juster

Literature:

[1] https://www.syensqo.com/en/brands/ixef-para

[2] https://plasticsfinder.envalior.com/en/datasheet/ForTii%C2%AE+Ace+MX53/O4A8W

[3] https://www.nexeoplastics.com/types/plastics-database-datasheet?id=2131&product=Ixef%C2%AE&grade=1022

[4] https://www.orinkoplastic.com/PA-6I-6T-And-MXD6-pl60644367.html

[5] https://www.polyarylamide.com/


Thursday, 13 November 2025

Plastic Part Failure Analysis - Example Breaking of Toy Helicopter Rotor Blades

Hello and welcome to new post in which we discuss one of my plastic part failure studies answering the question: Why did the toy helicopter rotor blades keep breaking?

Ever had a toy fail at the worst possible moment? That’s what happened with a rescue helicopter toy—kids reported the rotor blades snapping during “harder” rescue missions, always at the same spot. As someone who knows the pain of ordering spare parts, I had to dig deeper!

Here’s what I found:

Root Cause: The blades, made from ABS, consistently broke at the injection point—a natural weak spot. When force was applied (think: enthusiastic play!), stress concentrated here, causing failure.

Why Always the Same Spot? The injection point acts like a weak link in a fixed beam. Too much stress, and snap—it breaks right there (Figure 1).

Figure 1: Broken toy helicopter blade - injection molding point as root cause identified. 

How to Fix It?

1. Move the Injection Point: Shift it to the blade’s center using a conical gate, ensuring even filling and less stress (Figure 2).

Figure 2: Moving the injection point to the center allowing for even filling of both blade sides. 

2. Upgrade the Material: Switch to glass fiber reinforced ABS, increasing the needed force to break the rotor blade by 43% (Figure 3)!

Figure 3: Changing from ABS to ABS+GF10 increases the needed force to break the blade. 

3. Combine Both Approaches: For maximum durability.

This is a great reminder: optimal injection molded parts require attention to all five points of the Polymer Product Pentagram—Part Design, Material Selection, Mold Design, Machine Selection, and Molding Process.

Have you faced similar failures? Let’s connect here and share solutions! 

Thanks for reading & #findoutaboutplastics

Greetings,

Herwig Juster